Welcome to the forum KosherKing! I like your ambitious setup!
SME is giving you good advice regarding your control bucket. In my experience the SolarStorm 400 has a pretty small light footprint that conforms pretty tightly to its physical footprint, so you really want to get your plants right under the light. At the very least I would swap lids and make one of your corner buckets the control bucket.
I would also caution you against growing from seed under an LED. Plants grown from seed must be vegged until they show sex otherwise you risk stressing them and possibly ending up with hermaphroditic plants. In my experience it takes about a month to veg them until they show sex, and 6x 1 month old plants from seed will give you a 2' deep jungle. This will require expert pruning and training for the SolarStorm to be able to reach all of the growth tips due to the LED's inability to penetrate past a few inches of dense canopy at full flower. Of course, none of this applies if you are using autoflowers, in which case you should cram those buckets together as close as you can and maybe even ditch the control bucket.
I think you'll find that with lower powered lights you're much better off growing one or two big healthy plants than a bunch of big plants that are mostly stem and leaf due to improper lighting conditions. My SS400 test demonstrated to me that these lights really can't penetrate past 5" of dense canopy at full flower, so any lower branches are going to end up sucking up extra nutrients and only producing leafy popcorn buds. The best thing you can do is to gear your whole garden toward focusing light on as many growth tips as possible, while eliminating those that aren't receiving enough light (the ones that are stretching below the canopy). Only the growth tips with a front-row seat will produce dense buds under LED. YMMV as they say...
You might consider a 1 or 2 plant (1 plant is better IMO) SCROG grow. 1 plant bucket with 2 control buckets would work great for this kind of setup.
Hope this helps, and I can't wait to see the rest of your journal!